Fluorescence of the tri-cyclic adenine and isoguanine derivatives and their ribosides: possible analytical applications
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چکیده
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15 صفحه اولIsoguanine formation from adenine.
Several possible mechanisms underlying isoguanine formation when OH radical attacks the C(2) position of adenine (A C 2) are investigated theoretically for the first time. Two steps are involved in this process. In the first step, one of two low-lying A C 2⋅⋅⋅OH reactant complexes is formed, leading to C(2)-H(2) bond cleavage. Between the two reactant complexes there is a small isomerization ba...
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ژورنال
عنوان ژورنال: Acta Biochimica Polonica
سال: 2019
ISSN: 1734-154X,0001-527X
DOI: 10.18388/abp.2019_2885